Synthesis of the active sites of molybdoenzymes: MoO2(VI) and MoO(IV)-dithiolene complexes mimicking enzymatic reactions of sulphite oxidase with saturation kinetics
Modeling for the Active Site of Sulfite Oxidase: Synthesis, Characterization, and Reactivity of [MoVIO2(mnt)2]2-(mnt2- = 1,2-Dicyanoethylenedithiolate)
Authors: Samar K. Das; Pradeep K. Chaudhury; Dulali Biswas; Sabyasachi Sarkar
Stepwise reduction of electron-precise, six-electron, triangular, [Mo(Formula presented.)S4(CN)9]5− to electron-rich seven, eight and unstable nine-electron species resulting in core expansion to electron-precise, twelvee-lectron, tetrahedral, [Mo(Formula presented.)S4(CN)12]8−to electron-rich seven, eight and unstable nine-electron species resulting in core expansion to electron-precise, twelvee-lectron, tetrahedral, [Mo(Formula presented.)S4(CN)12]8−